According to Regulation (EC) No. 1907/2006 (REACH) and its latest amendment
SAFETY DATA SHEET
Issuing Date: 15-Apr-2021 Revision date 15-Apr-2021 Revision Number 1
Section 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE
COMPANY/UNDERTAKING
1.1. Product identifier
Product Form
Mixture
Product Name
Febreze Cotton Fresh
Product Identifier
91566524_RET_CLP_EUR_SAW
Synonyms
C-91566524-001
Product group
Trade Product
1.2. Relevant identified uses of the substance or mixture and uses advised against
Recommended use
Intended for general public
Main user category
SU 21 - Consumer uses: Private households (= general public = consumers)
Use category
PC3 - Air care products
Uses advised against
No information available
Product category
Aerosol
1.3. Details of the supplier of the safety data sheet
Details of the supplier of the safety
data sheet
Procter & Gamble UK Brooklands, Weybridge, Surrey, KT13 0XP, UK Tel: 01932
896000 Fax: 01932 896200
E-mail Address
1.4. Emergency telephone number
Emergency Telephone
(UK) Emergency Tel: 0800 328 8304 (IRL) Emergency Tel: 1800 509 497
Section 2: HAZARDS IDENTIFICATION
2.1. Classification of the substance or mixture
Classification and procedure used to derive the classification for mixtures according to Regulation (EC) 1272/2008 [CLP]
For the full text of the H-Statements mentioned in this Section, see Section 16.
Adverse human health effects and symptoms
No information available
2.2. Label elements
Label according to Regulation (EC) No. 1272/2008
Hazard pictograms
None
Signal word
Warning
Hazard statements
H229 - Pressurized container: May burst if heated
Precautionary statements
P102 - Keep out of reach of children
Aerosols
Category 3 - (H229)
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Avoid contact with skin and eyes
P305 + P351 - IF IN EYES: Rinse cautiously with water for several minutes
P501 - Dispose of contents/container to an appropriate local waste system
Use only as directed
P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources.
No smoking
P251 - Do not pierce or burn, even after use
P410 + P412 - Protect from sunlight. Do not expose to temperatures exceeding 50 °C
5% by mass of the contents are flammable
Contains Hexyl Cinnamal, Delta-Damascone
2.3. Other hazards
Other hazards which do not result
in classification
No presence of PBT and vPvB ingredients.
Section 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.1 Substances
Not applicable.
3.2 Mixtures
Chemical Name CAS No EC No REACH registration
number
Weight-% Classification according to
Regulation (EC) No.
1272/2008 [CLP]
M-Factor
(long-term
)
M-Factor
Alcohol 64-17-5 200-578-6 01-2119457610-43 1 - 5 Flam. Liq. 2(H225)
Eye Irrit. 2(H319)
Hexyl Cinnamal 165184-98-5 639-566-4 01-2119533092-50 <1 Skin Sens. 1B(H317)
Aquatic Acute 1(H400)
Aquatic Chronic 2(H411)
1 1
Delta-Damascone 57378-68-4 260-709-8 01-2119535122-53 <1 Acute Tox. 4 (Oral)(H302)
Skin Irrit. 2(H315)
Skin Sens. 1A(H317)
Aquatic Acute 1(H400)
Aquatic Chronic 1(H410)
Benzisothiazolinone 2634-33-5 220-120-9 <1 Acute Tox. 4 (Oral)(H302)
Skin Irrit. 2(H315)
Eye Dam. 1(H318)
Skin Sens. 1(H317)
Aquatic Acute 1(H400)
Aquatic Chronic 2(H411)
100
For the full text of the H-Statements mentioned in this Section, see Section 16.
Section 4: FIRST AID MEASURES
4.1. Description of first aid measures
Inhalation
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing. Immediately call a POISON CENTER or doctor/physician.
Skin contact
Take off contaminated clothing and wash before reuse. IF ON SKIN: Wash with plenty of
water and soap. If skin irritation or rash occurs: Get medical advice/attention. Discontinue
use of product.
Eye contact
Immediately call a POISON CENTER or doctor/physician. IF IN EYES: Rinse cautiously
with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing.
Ingestion
Immediately call a POISON CENTER or doctor/physician. IF SWALLOWED: Rinse mouth.
DO NOT induce vomiting.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries after inhalation
Coughing. Sneezing. Headache. Drowsiness. Dizziness.
Symptoms/injuries after skin
contact
Redness. Swelling. Dryness. Itching.
Symptoms/injuries after eye contact
Severe pain. Redness. Swelling. Blurred vision.
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Symptoms/injuries after ingestion
Oral mucosal or gastro-intestinal irritation. Nausea. Vomiting. Excessive secretion.
Diarrhea.
4.3. Indication of any immediate medical attention and special treatment needed
Refer to section 4.1.
Section 5: FIRE FIGHTING MEASURES
5.1. Extinguishing media
Suitable extinguishing media
Dry chemical powder. Alcohol resistant foam. Carbon dioxide (CO 2).
Extinguishing Media Which Must
Not Be Used For Safety Reasons
Solid water jet ineffective as extinguishing medium.
5.2. Special hazards arising from the substance or mixture
Explosion hazard
Product is not explosive.
Reactivity
No dangerous reaction known under conditions of normal use
5.3. Advice for firefighters
Special protective equipment for
fire-fighters
No specific firefighting instructions required.
Protective equipment and
precautions for firefighters
In case of inadequate ventilation wear respiratory protection.
Section 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency procedures
For non-emergency personnel
Wear suitable gloves and eye/face protection.
Advice for emergency responders
Wear suitable gloves and eye/face protection.
6.2. Environmental precautions
Environmental precautions
Prevent soil and water pollution. Avoid runoff to waterways and sewers.
6.3. Methods and material for containment and cleaning up
Methods for containment
Scoop absorbed substance into closing containers.
Methods for cleaning up
Small quantities of liquid spill:. take up in non-combustible absorbent material and shovel
into container for disposal. Large Spills:. contain released substance, pump into suitable
containers. This material and its container must be disposed of in a safe way, and as per
local legislation.
Other information
Not relevant.
6.4. Reference to other sections
Other information
Refer to Sections 8 and 13.
Section 7: HANDLING AND STORAGE
7.1. Precautions for safe handling
Advice on safe handling
Avoid contact with eyes. Avoid contact with skin. Use personal protective equipment as
required. Do not eat, drink or smoke when using this product. Do not handle until all safety
precautions have been read and understood. People suffering from perfume sensitivity
should be cautious when using this product. Ventilate the room after use.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures/Storage
conditions
Store in original container. Refer to section 10.
Incompatible products
Refer to section 10.
Incompatible Materials
Refer to section 10
Prohibitions on mixed storage
Not relevant.
Requirements for storage rooms
and containers
Store in a cool area. Store in a dry area.
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7.3. Specific end use(s)
Refer to section 1.2.
Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control parameters
National Occupational Exposure
Limits
Chemical Name CAS No Norway Ireland United Kingdom European Union
Alcohol 64-17-5 TWA: 500 ppm
TWA: 950 mg/m
3
STEL: 625 ppm
STEL: 1187.5 mg/m
3
STEL: 1000 ppm STEL: 3000 ppm
STEL: 5760 mg/m
3
TWA: 1000 ppm
TWA: 1920 mg/m
3
Derived No Effect Level (DNEL)
Workers
Chemical Name CAS No Worker - dermal,
short-term - systemic
Worker - inhalative,
short-term - systemic
Worker - dermal,
short-term - local
Hexyl Cinnamal 165184-98-5 0.525 mg/cm²
Delta-Damascone 57378-68-4 0.014 mg/cm²
Chemical Name CAS No Worker - inhalative,
short-term - local
Worker - dermal,
long-term - systemic
Worker - inhalative,
long-term - systemic
Alcohol 64-17-5 1900 mg/m³ 343 mg/kg bw/d 950 mg/m³
Hexyl Cinnamal 165184-98-5 6.28 mg/m³ 18.2 mg/kg bw/d 0.078 mg/m³
Delta-Damascone 57378-68-4 0.4 mg/kg bw/d 1.5 mg/m³
Chemical Name CAS No Worker - dermal, long-term -
local
Worker - inhalative, long-term -
local
Hexyl Cinnamal 165184-98-5 0.525 mg/cm²
Consumers
Chemical Name CAS No Consumer - inhalative,
short-term - local
Consumer - dermal,
short-term - local
Consumer - oral,
short-term - systemic
Alcohol 64-17-5 950 mg/m³
Hexyl Cinnamal 165184-98-5 4.71 mg/m³ 0.0787 mg/cm²
Delta-Damascone 57378-68-4 0.0086 mg/cm²
Chemical Name CAS No Consumer - oral,
long-term - systemic
Consumer - inhalative,
long-term - local
Consumer - dermal,
long-term - local
Alcohol 64-17-5 87 mg/kg bw/d
Hexyl Cinnamal 165184-98-5 0.056 mg/kg bw/d 0.0787 mg/cm²
Delta-Damascone 57378-68-4 0.25 mg/kg bw/d
Chemical Name CAS No Consumer - inhalative,
long-term - systemic
Consumer - dermal, long-term -
systemic
Alcohol 64-17-5 114 mg/m³ 206 mg/kg bw/d
Hexyl Cinnamal 165184-98-5 0.019 mg/m³ 9.11 mg/kg bw/d
Delta-Damascone 57378-68-4 1.5 mg/m
3
0.4 mg/kg bw.d
Predicted No Effect Concentration (PNEC)
Chemical Name CAS No Fresh Water Marine water Intermittent release
Alcohol 64-17-5 0.96 mg/L 0.79 mg/L 2.75 mg/L
Hexyl Cinnamal 165184-98-5 0.00138 mg/L 0.000138 mg/L 0.03 mg/L
Delta-Damascone 57378-68-4 0.007 mg/L 0.0007 mg/L
Chemical Name CAS No Freshwater sediment Marine sediment Sewage treatment
plant
Alcohol 64-17-5 3.6 mg/kg sediment dw 2.9 mg/kg sediment
dw
580 mg/L
Hexyl Cinnamal 165184-98-5 3.2 mg/kg sediment dw 0.064 mg/kg sediment
dw
10 mg/L
Delta-Damascone 57378-68-4 0.906 mg/kg sediment 0.0906 mg/kg 2.41 mg/L
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dw sediment dw
Chemical Name CAS No Soil air Oral
Alcohol 64-17-5 0.63 mg/kg soil dw
Hexyl Cinnamal 165184-98-5 9.51 mg/kg soil dw
Delta-Damascone 57378-68-4 0.177 mg/kg soil dw
8.2. Exposure controls
Appropriate engineering controls
No information available
Personal protective equipment
Protective personal equipment only required in case of professional use or for large packs
(not for household packs). For consumer use please follow recommendation as indicated
on the label of the product.
Hand Protection
Not relevant.
Eye Protection
Not relevant.
Skin and Body Protection
Not relevant.
Respiratory Protection
Not relevant.
Thermal hazards
Not relevant.
Environmental exposure controls
Prevent that the undiluted product reaches surface waters.
Section 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on basic physical and chemical properties
9.2. Other information
Property Value / Units Test Method / Notes
Appearance
Liquid
Physical state
Liquid
Color
Clear
Odor
pleasant (perfume)
Odor threshold
No Data Available Perceived odor at typical use conditions
pH
4.5 - 7
Melting point / freezing point
No Data Available Not available. This property is not relevant for the safety and
classification of this product
Initial boiling point and boiling
range
> 80 °C
Flash point
50 - 65 °C
Relative Evaporation Rate
(butylacetate=1)
0.95 – 1.50
Flammability
Not relevant
Upper/lower flammability or
explosive limits
No data available Not available. This property is not relevant for the safety and
classification of this product
Vapor pressure
No data available Not available. This property is not relevant for the safety and
classification of this product
Relative density
0.99 – 1.0
Solubility
Soluble in water
Partition coefficient
Not available Not available. This property is not relevant for the safety and
classification of this product
Autoignition temperature
No data available Not available. This property is not relevant for the safety and
classification of this product
Decomposition temperature
No data available Not available. This property is not relevant for the safety and
classification of this product
Viscosity
1 - 10 cps
Explosive properties
No data available Not applicable. This product is not classified as explosive as it
does not contain any substances which possesses explosive
properties CLP (Art 14 (2)).
Oxidizing properties
No Data Available
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Not applicable. This product is not classified as oxidizing as it
does not contain any substances which possesses oxidizing
properties CLP (Art 14 (2) )
91566524_RET_CLP_EUR_SAW - Febreze Cotton Fresh Revision date 15-Apr-2021
Other information
No information available.
Section 10: STABILITY AND REACTIVITY
10.1. Reactivity
No dangerous reactions known.
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
See section 10.1 on reactivity for more information.
10.4. Conditions to avoid
Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.
10.5. Incompatible materials
Not relevant.
10.6. Hazardous decomposition products
None under normal use conditions.
Section 11: TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects
Mixture
Acute toxicity
Not Classified. Based on the available data, the classification criteria are not met.
Skin corrosion/irritation
Not Classified. Based on the available data, the classification criteria are not met.
Serious eye damage/eye irritation
Not Classified. Based on the available data, the classification criteria are not met.
Skin sensitization
Not Classified. Based on the available data, the classification criteria are not met.
Respiratory sensitization
Not Classified. Based on the available data, the classification criteria are not met.
Germ cell mutagenicity
Not Classified. Based on the available data, the classification criteria are not met.
Carcinogenicity
Not Classified. Based on the available data, the classification criteria are not met.
Reproductive toxicity
Not Classified. Based on the available data, the classification criteria are not met.
STOT - single exposure
Not Classified. Based on the available data, the classification criteria are not met.
STOT - repeated exposure
Not Classified. Based on the available data, the classification criteria are not met.
Aspiration hazard
Not Classified. Based on the available data, the classification criteria are not met.
Substances in the mixture
Chemical Name CAS No Oral LD50 Dermal LD50 Inhalation LC50
Alcohol 64-17-5 10470 mg/kg bw (OECD
401)
- = 124.7 mg/L ( Rat ) 4 h
Delta-Damascone 57378-68-4 1400 mg/kg (rat) - -
Benzisothiazolinone 2634-33-5 1020 mg/kg - -
Section 12: ECOLOGICAL INFORMATION
12.1. Toxicity
Ecotoxicity effects
No known adverse effects on the functioning of water treatment plants under normal use
conditions as recommended. The product is not considered harmful to aquatic organisms
nor to cause long-term adverse effects in the environment.
Acute toxicity
Chemical Name CAS No Fish Algae/aquatic
plants
Crustacea Toxicity to
microorganisms
Alcohol 64-17-5 14200 mg/L (US EPA
E03-05; Pimephales
promelas; 96 h)
275 mg/L (//OECD
201; Chlorella
vulgaris; 72 h)
5012 mg/L (ASTM
E729-80;
Ceriodaphnia dubia;
48 h)
> 1000 mg/L (OECD
209; 3 h)
Hexyl Cinnamal 165184-98-5 1.7 mg/L (OECD 203; - - -
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Pimephales
promelas; 96 h)
Delta-Damascone 57378-68-4 0.97 mg/L(OECD
203; Oryzias latipes;
96h)
- - 241 mg/L (OECD
209; 3 h)
Benzisothiazolinone 2634-33-5 0.00997 mg/L
(Oncorhynchus
mykiss; 96 h)
- 0.02743 mg/L
(Daphnia magna; 48
h)
-
Chronic Toxicity
Chemical Name CAS No Toxicity to fish
(NOEC or ECx)*
Toxicity to algae
(NOEC or ECx)*
Toxicity to daphnia
and other aquatic
invertebrates
(NOEC or ECx)*
Toxicity to
Microorganisms
(NOEC or ECx)*
Alcohol 64-17-5 7900 mg/L (Oryzias
latipes; 8.33 d)
11.5 mg/L (//OECD
201; Chlorella
vulgaris; 3 d)
9.6 mg/L
(Ceriodaphnia dubia;
10 d)
12.2. Persistence and degradability
Persistence and degradability
.
Chemical Name CAS No Persistence and
degradability
Ready Biodegradation
Test (OECD 301)
Biodegradation Other
Tests
Alcohol 64-17-5 84% O2; 20 d 83%; 3 d
Hexyl Cinnamal 165184-98-5 97% O2; OECD 301 F;
87% (10 d)
97% O2; OECD 301 F;
87% (10 d)
12.3. Bioaccumulative potential
Bioaccumulative potential
.
Chemical Name CAS No Bioaccumulative potential
Octanol/water partition
coefficient
Alcohol 64-17-5 Not expected to bioaccumulate
due to the low log Kow (log Kow <
4)
-0.35
Hexyl Cinnamal 165184-98-5
5.3
Benzisothiazolinone 2634-33-5 Not measured
12.4. Mobility in soil
Mobility
.
Chemical Name CAS No log Koc
Alcohol 64-17-5 1 (QSAR PCKOCWIN v1.66)
12.5. Results of PBT and vPvB assessment
PBT and vPvB assessment
This mixture does not contain any substances that are assessed to be a PBT or a vPvB.
12.6 Other adverse effects
Other adverse effects
No information available.
Section 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste from Residues/Unused
Products
Dispose of in accordance with local regulations.
Disposal Recommendations
The waste codes/waste designations below are in accordance with EWC. Waste must be
delivered to an approved waste disposal company. Waste is to be kept separate from other
types of waste until its disposal. Do not throw waste product into the sewer.
Waste codes / waste designations
according to EWC / AVV
16 05 04* - gases in pressure containers (including halons) containing dangerous
substances
13.2 Additional information
Section 14: TRANSPORT INFORMATION
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IMDG
14.1 UN number or ID number
UN1950
14.2 UN proper shipping name
AEROSOLS
Description
UN1950, AEROSOLS, 2.2
14.3 Transport hazard class(es)
2.2
14.4 Packing group
Not relevant
14.5 Marine pollutant
Not regulated
EmS-No
F-D, S-U
14.7 Transport in bulk according to
Annex II of MARPOL and the IBC
Code
No information available
IMDG Comment
The shipper is responsible for identifying any exemptions, including Limited Quantity, that
may apply based on package size
IATA
14.1 UN number or ID number
UN1950
14.2 UN proper shipping name
AEROSOLS, NON-FLAMMABLE
Description
UN1950, AEROSOLS, NON-FLAMMABLE, 2.2
14.3 Transport hazard class(es)
2.2
14.4 Packing group
No information available
14.5 Marine pollutant
Not regulated
Comments
The shipper is responsible for identifying any exemptions, including Limited Quantity, that
may apply based on package size
ADR
14.1 UN number or ID number
UN1950
14.2 UN proper shipping name
AEROSOLS
Description
UN1950, AEROSOLS, 2.2
14.3 Transport hazard class(es)
2.2
14.4 Packing group
Not relevant
14.5 Marine pollutant
Not regulated
Classification code
5A
Labels
2.2
RID
14.1 UN number or ID number
UN1950
14.2 UN proper shipping name
AEROSOLS
Description
UN1950, AEROSOLS, 2.2
14.3 Transport hazard class(es)
2.2
14.4 Packing group
Not relevant
14.5 Marine pollutant
Not regulated
Classification code
5A
Labels
2.2
ADN
14.1 UN number
UN1950
14.2 UN proper shipping name
AEROSOLS
Description
UN1950, AEROSOLS, 2.2
14.3 Transport hazard class(es)
2.2
14.4 Packing group
Not relevant
14.5 Marine pollutant
Not regulated
Classification code
5A
Hazard label(s)
2.2
Limited quantity (LQ)
1 L
Ventilation
VE04
Equipment Requirements
PP
Section 15: REGULATORY INFORMATION
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15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Regulations
Regulation (EC) No. 1907/2006,
REACH Annex XVII Substances
subject to restriction on marketing
and use as amended
Contains no REACH substances with Annex XVII restrictions.
Regulation (EC) No. 1907/2006,
REACH Annex XVII Substances
subject to restriction on marketing
and use as amended
Contains no substance on the REACH candidate list.
Regulation (EC) No. 143/2011 Annex
XIV Substances Subject to
Authorisation
Contains no REACH Annex XIV substances.
CESIO Recommendations
The surfactant(s) contained in this preparation complies(comply) with the biodegradability
criteria as laid down in Regulation (EC) No.648/2004 on detergents. Data to support this
assertion are held at the disposal of the competent authorities of the Member States and
will be made available to them, at their direct request or at the request of a detergent
manufacturer.
Other regulations, restrictions and
prohibition regulations
Classification and procedure used to derive the classification for mixtures according to
Regulation (EC) 1272/2008 [CLP]. Registration, Evaluation, Authorization, and Restriction
of Chemicals (REACh) Regulation (EC 1907/2006). Aerosol Directive (75/324/EEC).
National regulatory information
15.2. Chemical safety assessment
Chemical Safety Assessment
No chemical safety assessment has been carried out for this mixture per REACH
regulation.
Section 16: OTHER INFORMATION
16.1 Indication of changes
Issuing Date:
15-Apr-2021
Revision date
15-Apr-2021
Revision Note
Change in SECTION 2: Hazards identification
16.2 Abbreviations and acronyms
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
ADN: European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways
ATE: Acute Toxicity Estimate
DNEL: Derived No Effect Level
EC50: Calculated concentration causing a 50% reduction in cellular reproduction
IATA: International Air Transport Association
IMDG: International Maritime Dangerous Goods Code
LC50: Lethal Concentration to 50% of a test population
LD50: Lethal Dose to 50% of a test population (Median Lethal Dose)
OECD - Organization for Economic Cooperation and Development
OEL: Occupational Exposure Limit
PBT: Persistent, Bioaccumulative and Toxic substance
PNEC(s): Predicted No Effect Concentration(s)
REACH- Registration, Evaluation and Authorization of Chemicals
vPvB: Very Persistent and Very Bioaccumulative
16.3 Classification and procedure used to derive the classification for mixtures according to Regulation (EC) 1272/2008
[CLP]
16.4 Full text of H-Statements referred to under sections 2 and 3
Physical Hazards
Aerosols Category 3 Expert judgment and weight of evidence determination
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H225 - Highly flammable liquid and vapor
H302 - Harmful if swallowed
H315 - Causes skin irritation
H317 - May cause an allergic skin reaction
H318 - Causes serious eye damage
H319 - Causes serious eye irritation
H400 - Very toxic to aquatic life
H410 - Very toxic to aquatic life with long lasting effects
H411 - Toxic to aquatic life with long lasting effects
This safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006
and its amendment Regulation (EU) 2015/830
16.5 Training Advice
Normal use of this product shall imply use in accordance with the instructions on the packaging.
16.6 Further information
Salts listed in Section 3 without a REACh Registration number are exempt, based on Annex V.
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental
requirements only. It should not therefore be construed as guaranteeing any specific property of the product.
End of Safety Data Sheet
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