10 - GENERAL PROCESSING
Drying of the material
Most of our general purpose and injection molding grades are
hygroscopic. More details are available from the Product Data
Sheet for each grade and/or the Quick Processing Reference.
This includes detailed information on processing setup and
unique features. Both documents are available on
www.santoprene.com
Effective moisture control ensures high quality parts that have
an appealing surface appearance. It is recommended for these
grades that the moisture be reduced to 0.08% or less before
processing. Specialized grades may have different drying
requirements. These will be spelled out on the Quick Processing
Reference for that grade. With any TPV, moisture impacts
processing, physical properties, product performance,
appearance, or a combination of these properties. Specifically,
moisture can cause poor melt quality, splay, voids, porosity,
rough surfaces, uneven appearance and/or silver streaking. For
some of the specialty bonding grades, drying is essential to
prevent material degradation.
Recommended best practices for drying
1. If possible, tumble blend colorants with the thermo plastic
pellets before drying in a desiccant/dehumidified hopper
dryer or vacuum oven. If colorants or additives are metered
at the hopper, pre dry colorants separately, unless not
recommended by the colorant supplier.
2. Open the drying hopper and make sure it is free of material.
Clean the hopper as needed. Be sure to follow standard
safety guidelines. Close the hopper and power it up.
3. Set the temperature control to ensure that air into the
hopper inlet is at the set point. We recommend using 80° C
(180 ° F) for most general purpose and injection molding
grades. Some specialty bonding grades have different drying
require ments. Please refer to the Product Data Sheet for
each grade or Quick Processing Reference for detailed
recommendations.
4. Once the dryer temperature is steady, check the dew point
indicator to ensure that a dew point temperature of 18 °C (0
°F) or lower exists. Fill the dryer hopper. Be sure to record
the material, grade, lot number, date and drying start up
time. As a suggestion, duplicate the same information on an
index or note card and attach it to the side of the dryer.
5. Dry virgin TPV pellets at least three hours, or dry blends of
virgin and regrind for four hours.
6. Once the drying cycle is complete, record the finished drying
time and move the TPV material to the processing
equipment. A best practice would be to have the drying
hopper integrated with the injection molding machine. This
insures that moisture cannot return to the dried material.
7. To eliminate the chance of an undried material “dead zone”
in the dryer, recycle some material from the bottom to the
top of the hopper.
8. A best practice would be to measure and confirm the
moisture level with a moisture analyzer. For best results, the
moisture level should not exceed 0.08%.
9. After the dryer is empty, power it down and again clean the
hopper.
Coloring
Parts molded with Santoprene TPV from ExxonMobil Chemical
can be produced on conventional molding equipment in any
color to match or com plement a finished product. Simply blend
neutral Santoprene TPV pellets with the appropriate colorant to
achieve nearly any color or hue desired. Pre colored TPV pellets
are available from several sources.
Solid color concentrates
Solid color concentrates are a versatile, pelletized form of a
colorant. These are widely used in the plastics industry due to
their stability, compatibility and dispersibility in almost any resin.
Color concentrates commonly consist of a pigment
compounded with a carrier resin such as polypro pylene or
polyethylene. Additionally these are well known for allowing
good control of color intensity in day to day consistency. They
are also dust free and easily used. Color concentrates can be
either tumble blended with the base resin or accurately metered
into a batch prior to processing. Color changes normally are
quick while minimizing cleanup.
The addition of any carrier resin can affect material properties,
including hardness, and it may slightly affect the material
processing and can affect part shrinkage. Some pigments also
affect these properties. Carrier less color concentrates are also
available to minimize property and processing effect.
Please follow the individual manufacture’s recom mendations
for loading. Typically this is about 1 to 5 weight percent,
depending on the application and the final color required.
Colorant carriers
We recommend using polyolefinic carriers such as
polypropylene with most colorable grades. The specialty
bonding grades may require specific or unique carrier or carrier-
less systems. Please refer to the Quick Processing Reference for
these recom men dations. Never use incompatible carriers. An
incompatible carrier can cause problems with melt quality,
which is evidenced by delamination in high shear regions or by
discoloration. Also, do not use polyvinyl chloride (PVC) as it is
not stable at normal TPV processing conditions.
As noted in the drying section above, most colorants absorb
moisture, so always follow proper drying procedures unless it
not recommended by the colorant supplier.