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TABLE 6.5 INCOMPATIBLE MATERIALS CHART
Chemical Is Incompatible With Chemical Is Incompatible With
Acetic Acid Chromic acid, nitric acid, hydroxyl compounds,
ethylene glycol, perchloric acid, peroxides,
permanganates
Fluorine Isolate from everything
Acetic anhydride Hydroxyl-containing compounds such as ethylene
glycol, perchloric acid
Hydrides Water
Acetone Concentrated nitric and sulfuric acid mixtures,
hydrogen peroxide
Hydrocarbons
(benzene, butane,
propane, gasoline,
turpentine, etc.)
Fluorine, chlorine, bromine, chromic acid, peroxides
Acetylene Chlorine, bromine, copper, fluorine, silver, mercury Hydrocyanic acid Nitric acid, alkalis
Alkali and alkaline
earth metals, such as
sodium, potassium,
lithium, magnesium,
calcium, powdered
aluminum
Carbon dioxide, carbon tetrachloride, other chlorinated
hydrocarbons (also prohibit the use of water, foam, and
dry chemical extinguishers on fires
Hydrofluoric acid
(anhydrous)
Hydrogen fluoride
Ammonia (aqueous or anhydrous)
Ammonia (anhydrous) Mercury (in manometers, for example), chlorine,
calcium hypochlorite, iodine, bromine, hydrogen
fluoride
Hydrogen
peroxide
Copper, chromium, iron, most metals or their salts, any
flammable liquid, combustible materials, aniline,
nitromethane
Ammonium nitrate Acids, metal powders, flammable liquids, chlorates,
nitrites, sulfur, finely divided organics, combustibles
Hydrogen sulfide Fuming nitric acid, oxidizing gases
Aniline Nitric acid, hydrogen peroxide Hypochlorites Acids, activated carbon
Arsenates and arsenites Any reducing agents Iodine Acetylene, ammonia (aqueous or anhydrous)
Azides Acids, heavy metals and their salts, oxidizing agents Mercury Acetylene, fulminic acid (produced in nitric acid-ethanol
mixtures), ammonia
Bromine Ammonia, acetylene, butadiene, butane, other
petroleum gases, sodium carbide, turpentine, benzene,
finely divided metals
Nitrates Acids, reducing agents
Calcium oxide Water Nitric acid
(concentrated)
Acetic acid, acetone, alcohol, aniline, chromic acid,
hydrocyanic acid, hydrogen sulfide, flammable liquids,
flammable gases, nitratable substances
Carbon (activated) Calcium hypochlorite, other oxidants Nitrites Acids, oxidizing agents
Carbon tetrachloride Sodium Nitroparaffins Inorganic bases, amines
Chlorates Ammonium salts, acids, metla powders, sulfur, finely
divided organics, combustibles
Oxalic acid Silver, mercury, and their salts
Chlorine Ammonia, acetylene, butadiene, butane, methane,
propane (or other petroleum gases), hydrogen, sodium
carbide, benzene, finely divided metals, turpentine
Oxygen Oils, grease, hydrogen, flammable materials (liquids,
solids, or gases)
Chlorine dioxide Ammonia, methane, phosphine, hydrogen sulfide Perchloric acid Acetic anhydride, bismuth and its alloys, alcohol, paper,
wood, grease, oils (all organics)
Chromic acid and
chromium trioxide
Acetic acid, naphthalene, camphor, glycerol,
turpentine, alcohol, other flammable liquids
Peroxides, organic Acids (organic or mineral); avoid friction, store cold
Copper Acetylene, hydrogen peroxide Phosphorus
(white)
Air, oxygen, alkalis, reducing agents
Cumene hydroperoxide Acids (organic or inorganic) Phosphorus
pentoxide
Alcohol, strong bases, water
Cyanides Acids Potassium Carbon tetrachloride, carbon dioxide, water
Flammable liquids Ammonium nitrate, chromic acid, hydrogen peroxide,
nitric acid, sodium peroxide, halogens
Potassium chlorate
(see also
chlorates)
Acids